IndiumV3, Russie, Analysis, bibRecord, 000685

EPR study of the structural phase transitions in chromium doped thallium indium disulphide

Identifieur interne : 000685 ( Russie/Analysis ); précédent : 000684; suivant : 000686

EPR study of the structural phase transitions in chromium doped thallium indium disulphide

Auteurs : RBID : Pascal:03-0199725

Descripteurs français

Pascal (Inist)
- RPE, Transformation phase, Dopage, Dépendance température, Largeur raie, Etude expérimentale, Champ cristallin, Addition chrome, Thallium sulfure, Indium sulfure, Monocristal, Réseau quadratique, Matériau ferroélectrique, TlInS2, In S Tl, 7630F, 6166F, 6150K.
Wicri :
- concept : Dopage.

English descriptors

KwdEn :
- Chromium additions, Crystal field, Doping, ESR, Experimental study, Ferroelectric materials, Indium sulfides, Line widths, Monocrystals, Phase transformations, Temperature dependence, Tetragonal lattices, Thallium sulfides.

Abstract

The results of low-temperature electron paramagnetic resonance (EPR) investigations of Cr³⁺ doped TlInS₂ single crystals in the temperature range 5-300 K are presented. Remarkable temperature dependences of the linewidth and resonance field of the main absorption peak in EPR spectra of Cr³⁺ ion were observed. These peculiarities are attributed to the well-known successive phase transitions between 200 and 220 K. Considerable changes of EPR spectra were observed at the temperatures below 80 K, which are associated with strong line broadening, splitting, and appearance of additional peaks. Such transformations are considered as results of tetragonal distortions of InS₄ tetrahedra. An active group responsible for the previously reported phase transitions at the temperatures 216, 204 and 79 K has been determined.

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Pascal:03-0199725

Le document en format XML

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<author><name sortKey="Mikailov, F A" uniqKey="Mikailov F">F. A. Mikailov</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Physics, Gebze Institute of Technology</s1>
<s2>Gebze, 41400, Kocaeli</s2>
<s3>TUR</s3>
<sZ>1 aut.</sZ>
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<sZ>4 aut.</sZ>
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<country>Turquie</country>
<wicri:noRegion>Gebze, 41400, Kocaeli</wicri:noRegion>
</affiliation>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Institute of Physics, Azerbaijan Academy of Sciences</s1>
<s2>370143, Baku</s2>
<s3>AZE</s3>
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<country>Azerbaïdjan</country>
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<author><name sortKey="Rameev, B Z" uniqKey="Rameev B">B. Z. Rameev</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Physics, Gebze Institute of Technology</s1>
<s2>Gebze, 41400, Kocaeli</s2>
<s3>TUR</s3>
<sZ>1 aut.</sZ>
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<country>Turquie</country>
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<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Kazan Physical-Technical Institute, 10/7, Sibirsky Trakt</s1>
<s2>420029 Kazan</s2>
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<country>Russie</country>
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<author><name sortKey="Kulibekov, A M" uniqKey="Kulibekov A">A. M. Kulibekov</name>
<affiliation wicri:level="1"><inist:fA14 i1="04"><s1>Department of Physics, Mugla University</s1>
<s2>48000, Mugla</s2>
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<country>Turquie</country>
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<author><name sortKey="Sent Rk, E" uniqKey="Sent Rk E">E. Sent Rk</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Physics, Gebze Institute of Technology</s1>
<s2>Gebze, 41400, Kocaeli</s2>
<s3>TUR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<wicri:noRegion>Gebze, 41400, Kocaeli</wicri:noRegion>
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<affiliation wicri:level="1"><inist:fA14 i1="05"><s1>Department of Physics, Sakarya University</s1>
<s2>54100, Sakarya</s2>
<s3>TUR</s3>
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<country>Turquie</country>
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<author><name sortKey="Aktas, B" uniqKey="Aktas B">B. Aktas</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Physics, Gebze Institute of Technology</s1>
<s2>Gebze, 41400, Kocaeli</s2>
<s3>TUR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<country>Turquie</country>
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<date when="2003">2003</date>
<idno type="stanalyst">PASCAL 03-0199725 INIST</idno>
<idno type="RBID">Pascal:03-0199725</idno>
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</publicationStmt>
<seriesStmt><idno type="ISSN">0304-8853</idno>
<title level="j" type="abbreviated">J. magn. magn. mater.</title>
<title level="j" type="main">Journal of magnetism and magnetic materials</title>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Chromium additions</term>
<term>Crystal field</term>
<term>Doping</term>
<term>ESR</term>
<term>Experimental study</term>
<term>Ferroelectric materials</term>
<term>Indium sulfides</term>
<term>Line widths</term>
<term>Monocrystals</term>
<term>Phase transformations</term>
<term>Temperature dependence</term>
<term>Tetragonal lattices</term>
<term>Thallium sulfides</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>RPE</term>
<term>Transformation phase</term>
<term>Dopage</term>
<term>Dépendance température</term>
<term>Largeur raie</term>
<term>Etude expérimentale</term>
<term>Champ cristallin</term>
<term>Addition chrome</term>
<term>Thallium sulfure</term>
<term>Indium sulfure</term>
<term>Monocristal</term>
<term>Réseau quadratique</term>
<term>Matériau ferroélectrique</term>
<term>TlInS2</term>
<term>In S Tl</term>
<term>7630F</term>
<term>6166F</term>
<term>6150K</term>
</keywords>
<keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Dopage</term>
</keywords>
</textClass>
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<front><div type="abstract" xml:lang="en">The results of low-temperature electron paramagnetic resonance (EPR) investigations of Cr<sup>3+</sup>
 doped TlInS<sub>2</sub>
 single crystals in the temperature range 5-300 K are presented. Remarkable temperature dependences of the linewidth and resonance field of the main absorption peak in EPR spectra of Cr<sup>3+</sup>
 ion were observed. These peculiarities are attributed to the well-known successive phase transitions between 200 and 220 K. Considerable changes of EPR spectra were observed at the temperatures below 80 K, which are associated with strong line broadening, splitting, and appearance of additional peaks. Such transformations are considered as results of tetragonal distortions of InS<sub>4</sub>
 tetrahedra. An active group responsible for the previously reported phase transitions at the temperatures 216, 204 and 79 K has been determined.</div>
</front>
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<sZ>2 aut.</sZ>
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<fA14 i1="02"><s1>Institute of Physics, Azerbaijan Academy of Sciences</s1>
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<sZ>3 aut.</sZ>
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<fA14 i1="05"><s1>Department of Physics, Sakarya University</s1>
<s2>54100, Sakarya</s2>
<s3>TUR</s3>
<sZ>4 aut.</sZ>
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<fC01 i1="01" l="ENG"><s0>The results of low-temperature electron paramagnetic resonance (EPR) investigations of Cr<sup>3+</sup>
 doped TlInS<sub>2</sub>
 single crystals in the temperature range 5-300 K are presented. Remarkable temperature dependences of the linewidth and resonance field of the main absorption peak in EPR spectra of Cr<sup>3+</sup>
 ion were observed. These peculiarities are attributed to the well-known successive phase transitions between 200 and 220 K. Considerable changes of EPR spectra were observed at the temperatures below 80 K, which are associated with strong line broadening, splitting, and appearance of additional peaks. Such transformations are considered as results of tetragonal distortions of InS<sub>4</sub>
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<s5>06</s5>
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<fC03 i1="14" i2="3" l="FRE"><s0>TlInS2</s0>
<s4>INC</s4>
<s5>52</s5>
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</fN21>
<fN82><s1>PSI</s1>
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EPR study of the structural phase transitions in chromium doped thallium indium disulphide

EPR study of the structural phase transitions in chromium doped thallium indium disulphide

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri